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Purpose: To assess the pain, swelling, infection, and alteration in sensation following the flapless placement of zygomatic implants guided by dynamic navigation. Materials and Methods: A randomized controlled trial was conducted on 20 patients. In group 1, the placement of the zygomatic implants was carried out without reflecting a mucoperiosteal flap (flapless). In group 2, a mucoperiosteal flap was raised (flapped). Two zygomatic implants were placed in each patient (one on each side) under local anesthesia, guided by dynamic navigation. Postoperative evaluations included pain (using the visual analogue scale [VAS]), swelling (using standard measurements), maxillary sinus infection, and alteration of sensation (using mechanical stimuli, thermal threshold detection, and a two-point discrimination test). The assessments were carried out at 2 days, 1 week, and then 1, 2, and 3 months postoperatively. Results: In group 1, all implants except for one were successfully osseointegrated. Immediate postoperative pain and swelling were both significantly greater in group 2 (P < .01). No alteration in sensation was detected in any case in the two groups. There were a total of three cases of chronic sinusitis: one in group 1 and two in group 2. Conclusions: The flapless placement of zygomatic implants guided by dynamic navigation and under local anesthesia improves postoperative recovery. [ABSTRACT FROM AUTHOR]

Bentonite is a recommended material for the multiple barriers in the final disposal of low-level radioactive waste (LLW) to prevent groundwater intrusion and nuclear species migration. However, after drying-wetting cycling during the repository construction stage and ion exchange with the concrete barrier in the long-term repository, the bentonite mechanical behaviors, including swelling capacity and hydraulic conductivity, would be further influenced by the groundwater intrusion, resulting in radioactive leakage. To comprehensively examine the factors on the mechanical characteristics of bentonite, this study presented scenarios involving MX-80 and KV-1 bentonites subjected to drying-wetting cycling and accelerated ion migration. The experiments subsequently measured free swelling, swelling pressure, and hydraulic conductivity of bentonites with intrusions of seawater, high pH, and low pH solutions. The results indicated that the solutions caused a reduction in swelling volume and pressure, and an increase in hydraulic conductivity. Specifically, the swelling capability of bentonite with drying-wetting cycling in the seawater decreased significantly by 60%, while hydraulic conductivity increased by more than three times. Therefore, the study suggested minimizing drying-wetting cycling and preventing seawater intrusion, ensuring a long service life of the multiple barriers in the LLW repository.

Aims: To measure the effects of leukocyte and platelet-rich fibrin (L-PRF) on swelling and saliva levels of interleukin-6 (IL-6) at different intervals after surgical removal of the impacted lower third molar. Materials and Methods: The study included 30 patients aged between (17-35) years who needed surgical removal of an impacted lower third molar under local anesthesia. Patients were divided into two groups, L-PRF, and control groups. In the L-PRF group, the L-PRF was prepared from the patient’s own blood, and the blood was centrifuged for 12 minutes at 2700 rpm. The clot was inserted in the socket after surgical removal of the impacted lower wisdom teeth, while in the control group, no material was inserted inside the socket. Facial swelling was assessed preoperatively, 2nd, and 7th days after the operation. Saliva level of IL-6 was measured (using ELISA) preoperatively and 7th day after the operation. Results: Regarding swelling within groups, in the L-PRF group, swelling showed a significant difference, while in the control group, there was no statistically significance difference. Between groups, there was no statistical difference in swelling between the preoperative and 2nd day postoperatively, and between 2nd and 7th day after the operation. Regarding IL-6 levels on the 7th postoperative day, there were no statistically significant differences between both groups. Conclusions: L-PRF decreases swelling following surgery within the group, but differences in swelling and levels of IL-6 in saliva among groups were not statistically significant, after surgical removal of the impacted mandibular third molar.

Conformance control or water shut-off is a technique used to improve oil recovery. During conformance control, polymers block high permeability water areas and redistribute water drive toward unswept oil zones. In this study, co-polymers (denoted ATP-PGV/AM-co-AMPS) were synthesized using acrylamide (AM) and 2-acrylamide-2-methylpropane sulfonic acid (AMPS) as the monomers, polyethylene glycol (PEG)-200 and methylenebisacrylamide (MBA) as the crosslinkers, attapulgite (ATP) and bentonite (PGV) as the clay types, and ammonium persulfate (APS) as the initiator, in addition to paraffin oil and surfactants. Samples were synthesized using inverse emulsion polymerization with different concentrations of monomers, crosslinkers, and clays, and they were characterized using Fourier-transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDX). FTIR spectra of the samples confirmed the existence of sulfonate and hydroxyl groups, which are important for polymer swelling. SEM-EDX images indicated that the morphology and elemental composition were different before and after swelling, confirming the occurrence of swelling. Moreover, samples were placed in sodium chloride solution (20,000 ppm) for 7 days to evaluate swelling at both room temperature and 90 °C. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were used to determine the thermal characteristics of the microparticles. Finally, rheological measurements were used to assess the deformation and rheological behavior of the hydrogels. The results showed that after 1 day, good swelling without loss of mechanical strength was achieved with the composite synthesized using 10% AM, 15% AMPS, 6% PGV, and 10% ATP.

Deuterium-tritium fusion reactions produce energy in the form of 14.1 MeV neutrons, and hence fusion reactor components will be exposed to high energy neutron irradiation while also being subjected to thermal, mechanical and magnetic loads. Exposure to neutron irradiation has numerous consequences, including swelling and dimensional changes, comparable in magnitude to the peak transient thermal deformations occurring in plasma-facing components. Irradiation also dynamically alters the various thermo-mechanical properties, relating temperature, stress and swelling in a strongly non-linear way. Experimental data on the effect of neutron exposure spanning the design parameter space are very sparse and this highlights the relevance of computer simulations. In this study we explore the equivalence between the body force/surface traction approach and the eigenstrain formalism for treating anisotropic irradiation-induced swelling. We find that both commercial and massively parallelised open source software for finite element method (FEM) simulations are suitable for assessing the effect of neutron exposure on the mechanically loaded reactor components. We demonstrate how two primary effects of irradiation, radiation swelling and the degradation of thermal conductivity, affect the distributions of stress and temperature in the divertor of the ITER tokamak. Significant uncertainties characterising the magnitude of swelling and models for treating it suggest that on the basis of the presently available data, only an order of magnitude estimate can be given to the stress developing in reactor components most exposed to irradiation during service. [ABSTRACT FROM AUTHOR]

AbstractMolybdenum disulfide (MoS2), a two-dimensional inorganic molecule, has lately been studied in medical research with regard to carrying pharmaceuticals due to its distinctive characteristics. A biodegradable polymer system applicable in cancer drug delivery can be created with the addition of MoS2. In our research described in this paper, we investigated the influence of the amount of MoS2 on the characteristics and performance of our novel gel blend. It was aimed to prepare a new gel blend, which we thought would have the potential to be used as a stimulus-sensitive, polymeric hydrogel as a carrier in the triple negative breast cancer (TNBC) drug delivery system, with the MoS2 added to the polyethylene glycol (PEG)/κ-carrageenan combination. This 2D material (MoS2) impacted the hydrogel by improving the transmittance, swelling, and elasticity performance compared to the normal no MoS2 structure of the polymeric gel. The polymer blend characteristics were mainly tested using UV-VIS spectrophotometry and gravimetric analysis. The varied properties of these gel mixtures were investigated using five different mass ratios of MoS2. The 5 mg MoS2/(PEG)/κ-carrageenan gel was the best sample investigated in terms of the elasticity. The results of the study demonstrated that our gel system can be utilized for precisely targeted and regulated delivery of cancer drugs. To create preliminary data for this near future goal, the release mechanism of the Doxorubicin drug loaded into the produced gel were examined. [ABSTRACT FROM AUTHOR]

In a growing world population scenario, greater demand for food and in turn agricultural input is expected in the coming decades. The development of innovative sustainable amendments and fertilizers such as hydrogels (HGs) relies on this context. HGs are defined as 3D polymeric networks with the ability to absorb and retain a large amount of water (i.e., swellability). HGs swellability makes them ideal platforms for water- and nutrient-controlled release. The literature reflects a notable diversity in HGs composition, properties, and impacts on agroecosystems, resulting in the dissemination of information across multiple publications. Within this context, the primary aim of this scientific review is to systematically compile, critically evaluate, and synthesize the latest findings and relevant literature pertaining to the application of HGs in agroecosystems. We found that this class of materials was consistently found on soil bulk density, crop available water, soil electrical conductivity, cation exchange capacity and main cereal or legume crops performances particularly under moderate water deficit conditions, suggesting their effectiveness for arid and semi- arid areas. Encouraging results were also found on pesticide, agrochemicals, and microorganisms delivering. Thus, the delivery of agronomic inputs with loaded-HG may play a key role in forthcoming agriculture that would minimize the agronomic impact on the environment. Nevertheless, some critical issues still remain open, concerning: (i) the decreased of HG effectiveness following wetting and drying cycles, (ii) the impact of Na+ contained in HG on crop cells, (iii) the HG effect on soil saturated hydraulic conductivity and pH, and (iv) HG biodegradability and their fate into the environment. In conclusion, HGs seem a promising technology to reach/maintain food security and soil health, but future research should address the development of well-defined protocols for producing biowaste-derived HG that will ensure their biodegradability and non-toxicity and will disclose new insights into a circular economy approach agronomy. One of the biggest challenges would be the synthesis of “smart” HG able to respond to environmental stimuli triggering molecule(s) release in soil. [ABSTRACT FROM AUTHOR]

Liquid silicone rubber (LSR) garners attention across a diverse range of industries owing to its commendable fluidity and heat resistance. Nonetheless, its mechanical strength and oil resistance fall short compared to other rubbers, necessitating enhancement through the incorporation of a suitable filler. This research focuses on reinforcing LSR using carbon black (CB) particles as a filler, evaluating the mechanical properties and oil resistance of neat LSR, and LSR containing up to 3 wt% of CB filler. CB was added in powder form to investigate its effect on LSR. When LSR was impregnated with oil, the deterioration of rubber was noticeably observed under high-temperature conditions compared to room-temperature conditions. Consequently, the mechanical properties and oil resistance, excluding the permanent compression reduction rate, tended to increase as the filling content of CB increased compared to the unfilled state. Notably, in the specimen with 2 wt% CB filler, the tensile modulus increased significantly by 48% and the deterioration rate was reduced by about 50% under accelerated deterioration conditions. Additionally, the swelling rate in oil decreased by around 14%. This validates a notable improvement in both mechanical properties and oil resistance. Based on the identified mechanism for properties enhancement in this study, CB/LSR composite is expected to have a wide range of applications in fields such as gaskets, oil seals, and flexible sensors. [ABSTRACT FROM AUTHOR]

Surgical sutures are gold‐standard wound closure devices. However, they are unable to form a tight seal with surrounding tissues, raising the risks of body fluid leakage and surgical site infection. Additionally, the use of sutures can result in cracking at suture roots, damage and micro‐trauma to soft tissues due to the slicing and compression of suture fibers after their placement. Bioadhesives capable of mimicking natural biological interfaces are appealing alternatives, but they cannot achieve the same level of strength as conventional surgical sutures. Here, a tough adhesive puncture sealing (TAPS) suture, featuring swelling‐triggered bioadhesion to mend the gap between the suture and the surrounding tissues with a soft yet tough adhesive interface is reported. This unique design principle of TAPS sutures is applicable to diverse soft tissues of various defect sizes and can be controlled by modulating the hydrogel swelling kinetics. The advantages of the TAPS sutures for meniscal tear repair and intestine tissue sealing ex vivo, corroborates their favorable applications in managing mechanically active musculoskeletal and gastrointestinal tissues are demonstrated. The design and performance of the TAPS sutures offer extensive possibilities for redesigning surgical tools and developing next‐generation medical devices for wound management and tissue repair. [ABSTRACT FROM AUTHOR]

Sorbents are promising materials for applications in atmospheric water harvesting, thermal energy storage, and passive cooling, thereby addressing central challenges related to water scarcity and the global energy transition. Recently, hygroscopic hydrogel composites have emerged as high‐performance sorbents. However, many of these systems are fabricated with unsustainable and costly sorbent materials, which hinders their wide deployment. Here, the synthesis of high‐performance, cost‐efficient polyacrylamide hydrogels loaded with unprecedented amounts of calcium chloride is demonstrated. To this end, the swelling procedure of polyacrylamide hydrogels in aqueous calcium chloride solutions is optimized. The achievable salt loading in the hydrogel is characterized as a function of temperature, calcium chloride concentration in the swelling solution, and the hydrogel preparation conditions. The obtained hydrogel‐salt composites are shown to be stable under repeated sorption‐desorption cycling and enable water uptakes of 0.92 and 2.38 grams of water per gram of dry materials at 30% and 70% relative humidity, respectively. The resulting cost‐performance ratio substantially exceeds lithium chloride‐based systems. Further, the mechanistic insights on hydrogel salt interactions can guide the design of sustainable and low‐cost sorbent materials for future applications in water and energy. [ABSTRACT FROM AUTHOR]

Amphiphilic polymer gels show environmentally sensitive mechanical properties depending on the solvent polarity, which makes them useful for applications in soft contact lenses, membranes, drug delivery systems, and tissue engineering. To rationally design the material properties for such applications, a sound knowledge about the mechanical properties at different solvency states is necessary. To acquire such knowledge, amphiphilic networks are prepared by hetero‐complementary coupling of amine‐terminated tetra‐poly(ethylene glycol) (t‐PEG‐NH2) with 2‐(4‐nitrophenyl)‐benzoxazinone terminated tetra‐poly(ε‐caprolactone) (t‐PCL‐Ox). The mechanical properties are investigated on different length‐scales and under non‐selective and selective solvent conditions using shear rheometry and atomic force microscopy (AFM). The swelling as well as the modulus in good solvent are in accord with scaling laws found for other four‐arm star‐shaped polymer networks and theoretical predictions. The swelling in selective solvent reveals a concentration‐independent volume swelling degree and a nearly linear scaling of the modulus with concentration. The surface topography probed by AFM reveals microphase‐separated structures in the range of 20 nm. Similar modulus values are obtained for bulk films in water using the complementary methods of atomic force microscopy and rheometry. The data are compared with pure hydrophilic networks to identify the effect of amphiphilicity on the material properties. [ABSTRACT FROM AUTHOR]

AbstractVanadium is a typical low-activation metal and has the advantages of lower neutron irradiation activation, better mechanical properties at high temperature, and higher compatibility with the liquid lithium blanket. However, the effect of helium on the formation of irradiation defects in vanadium has not been adequately explored at low temperatures (below 723 K). Helium ion irradiations of 18 keV up to 0.54 displacement per atom were employed to study the temperature-dependent behavior of irradiation defects in vanadium at 523, 623, and 723 K. Helium bubbles were observed in vanadium under irradiations at all temperatures, but no dislocation loops were observed. With the increase of irradiation temperature, the average size of helium bubbles and swelling increased, and the density of helium bubbles decreased. It is noteworthy that the average size of helium bubbles and swelling increased significantly when the irradiation temperature increased from 623  to 723 K. In addition, pentagonal helium bubbles, helium bubbles nucleated at the grain boundary, and combinations between helium bubbles were observed. [ABSTRACT FROM AUTHOR]

Stimuli‐responsive materials have recently gained significant attention in the field of soft robotics, sensors, and biomimetic devices. The most facile way for the fabrication of such materials remains to endow bilayer structures which are fabricated with the combination of active and passive layers. Although, easily fabricated, these structures suffer from the generation of stress points between connection areas. In this work we develop a method to create a thin film with controlled cross‐link variation across its thickness. The cross‐link gradient is achieved through polymerization induced diffusion of dithiol molecules in thiol‐ene network. As a result, the film exhibits bending deformation upon illumination with light or exposure to a chemical solvent, thereby demonstrating dual responsiveness. Light actuation of the film is achieved via photothermal effects due to the incorporation of dye into the system which can absorb UV light and heat the network. While solvent induced actuation is due to anisotropic swelling. Furthermore, the straightforward fabrication procedure allows for the creation of more complex deformations by patterning the film using a photomask during photopolymerization. [ABSTRACT FROM AUTHOR]

Pressure‐induced swelling has been reported earlier for several hydrophilic layered materials. MXene Ti3C2Tx is also a hydrophilic layered material composed by 2D sheets but so far pressure‐induced swelling is reported for this material only under conditions of shear stress at MPa pressures. Here, high‐pressure experiments are performed with MXenes prepared by two methods known to provide "clay‐like" materials. MXene synthesized by etching MAX phase with HCl+LiF demonstrates the effect of pressure‐induced swelling at 0.2 GPa with the insertion of additional water layer. The transition is incomplete with two swollen phases (ambient with d(001) = 16.7Å and pressure‐induced with d(001) = 19.2Å at 0.2 GPa) co‐existing up to the pressure point of water solidification. Therefore, the swelling transition corresponds to change from two‐layer water intercalation (2L‐phase) to a never previously observed three‐layer water intercalation (3L‐phase) of MXene. Experiments with MXene prepared by LiCl+HF etching have not revealed pressure‐induced swelling in liquid water. Both MXenes also show no anomalous compressibility in liquid methanol. The presence of pressure‐induced swelling only in one of the MXenes indicates that the HCl+LiF synthesis method is likely to result in higher abundance of hydrophilic functional groups terminating 2D titanium carbide. [ABSTRACT FROM AUTHOR]

Wood waste, which constitutes an important component of solid waste, is produced by the wood industry, and especially in the processing one. The wood industry includes tree bark, sawdust, planer shavings, sander dust etc. produces unwanted products and/or wastes. This study investigated the usability of sawdust of fruit trees in the production of Medium Density Fiberboard (MDF) and some technological properties of the produced MDF panels. Sawdust of fruit trees was mixed to beech fibers at the ratio of 10, 20 and 30% by weight. The mats were manually formed using 13% urea formaldehyde and pressed at a temperature of 185°C for 8 min in a computer control press. The MDF panel samples of water absorption (WA), thickness swelling (TS), surface hardness, surface roughness, MOR and MOE were investigated. It was determined that the values of WA and TS decreased with increasing the ratio of sawdust. Modulus of rupture (MOR), modulus of elasticity (MOE), surface hardness, surface roughness parameters (Ra, Rq and Rz) values of panel samples increased with increasing the ratio of sawdust from panels. Based on these results, it is advisable that wood sawdust fruit-trees can be used as an alternative raw material source in MDF production. [ABSTRACT FROM AUTHOR]

A 58-year-old man with a history of diabetes type I and chronic coronary syndrome who underwent coronary artery bypass grafting (CABG) 7 years before was admitted to a cardiology unit for unplanned cardiac catheterization because of dyspnea and chest pain at rest. Femoral access was chosen because of the previous CABG and a vascular closure device (VCD) was used at the end of the procedure. Because of femoral artery rupture during VCD implantation, surgical vascular repair was performed. About 45 days later, the patient experienced a growing inguinal swelling at the site of vascular access in the absence of fever and clinical features of inflammation. The swelling became painful over time. Despite the most probable hypothesis of a hematoma, pseudoaneurysm, and inguinal abscess, a final diagnosis of lymphocele was made. [ABSTRACT FROM AUTHOR]

Legumes are a cost-effective source of proteins and abundant starch, a biodegradable substance, providing human nutrition and serving various food sectors globally. Some of the neglected (underutilised) legumes can also be used as the cheapest source of starch. Therefore, the present study was conducted to determine the physicochemical characteristics of jack bean (Canavalia ensiformis) starch - a legume not widely known so underutilised. The starch was isolated from the bean by standard method to study its various properties. One-way analysis of variance was employed to verify a significant difference at the 5% significance level. The jack bean yielded 30.98% of starch. The starch's moisture, ash, fat, protein, fiber, and carbohydrate content were 9.67%, 0.19%, 0.27%, 0.56%, 0.27%, and 89.28% respectively. The physicochemical properties were also determined. The apparent and total amylose contents were 43.82% and 47.78%, respectively, with 7.66% of amylose leaching at 95° C. The water and oil absorption capacities were 2.31 and 2.56 g/g, respectively, while emulsion capacity and stability were 62.30 and 71.38 %, respectively. The solubility and swelling power of jack bean starch increased with temperature from 55 to 95°C. The effect of starch concentrations (6, 8, and 10%) on freeze-thaw stability revealed that water expelled decreased as starch content increased. Nevertheless, a comprehensive investigation has not been conducted into the distinct functional characteristics and other attributes of jack bean starch. This study could provide new opportunities for conventional starch industries that rely on starch from sources like cereals, tubers, and rhizomes. [ABSTRACT FROM AUTHOR]

Brain edema is considered as a common feature associated with hepatic encephalopathy (HE). However, its central role as cause or consequence of HE and its implication in the development of the neurological alterations linked to HE are still under debate. It is now well accepted that type A and type C HE are biologically and clinically different, leading to different manifestations of brain edema. As a result, the findings on brain edema/swelling in type C HE are variable and sometimes controversial. In the light of the changing natural history of liver disease, better description of the clinical trajectory of cirrhosis and understanding of molecular mechanisms of HE, and the role of brain edema as a central component in the pathogenesis of HE is revisited in the current review. Furthermore, this review highlights the main techniques to measure brain edema and their advantages/disadvantages together with an in-depth description of the main ex-vivo/in-vivo findings using cell cultures, animal models and humans with HE. These findings are instrumental in elucidating the role of brain edema in HE and also in designing new multimodal studies by performing in-vivo combined with ex-vivo experiments for a better characterization of brain edema longitudinally and of its role in HE, especially in type C HE where water content changes are small. [ABSTRACT FROM AUTHOR]

Polymer matrix tablets are an important drug-delivery system widely used for oral drug administration. Understanding the tablet hydration process, both experimentally and theoretically, is, thus, very important for the development of drug delivery systems that exhibit high drug loading capacity and controlled release potential. In this study, we used magnetic resonance microscopy (MRM) to nondestructively and dynamically analyze the water hydration process of xanthan-based tablets. The swelling process was characterized by well-resolved fronts of erosion, swelling, and penetration. The experimental results were complemented by numerical simulations of the polymer matrix hydration process. In the simulations, the polymer tablet matrix was modeled as an assembly of interacting chains with embedded drug particles, while its hydration process was mediated by interaction with solvent particles. The swelling dynamics were modeled within a Monte Carlo-based bond fluctuation model (BFM) that elegantly accounted for steric and nearest-neighbor interactions. This study provides an efficient experimental–theoretical approach for the study of polymer matrix swelling processes. [ABSTRACT FROM AUTHOR]

Water plays an important role in the properties of cellulose. In materials design, the water uptake of cellulose has been traditionally seen as a drawback, since water reduces mechanical resistance of paper and cardboard, and at high hydration, cellulose-based products are disintegrated. However, recently, the hydration of cellulose has been considered as an advantage to design water-responsive soft actuators. In Nature, water is the fuel for several plant functions that involve motion, such as the seed release or the plant protection from high temperature and radiation. Inspired by these natural systems, cellulose-based actuators have been designed to display different movements (bending, twisting, curling) in response to water. Biopolymer structuration inducing anisotropy within the system allows the asymmetric expansion of layers, which results in macroscopic movement. This review gives an overview of the soft actuators triggered by the hydration/dehydration processes of cellulose. We present representative examples of water-triggered natural actuators, which have inspired researchers to design anisotropic cellulose-based materials that develop controlled movement in response to water. [ABSTRACT FROM AUTHOR]

This study deals with preparing and characterizing polyvinyl alcohol/egg white/montmorillonite bionanocomposite hydrogels as antibacterial drug delivery systems. The cyclic freezing/thawing method was utilized to fabricate the hydrogels. To study the performance of the prepared hydrogels as drug delivery systems, amoxicillin, as a model antibiotic drug, was loaded into the hydrogels by mixing with the precursor polymer solution and gelation. From the diverse microstructural characterization techniques, i.e. XRD, SEM, AFM, DLS, and gel fraction estimation, it was possible to infer that montmorillonite has been successfully incorporated into the hydrogel network and acted as an additional crosslinker to bind the chains of egg white and polyvinyl alcohol. Scrutinizing the physical properties of the produced hydrogels demonstrated that increasing incorporated montmorillonite content adversely affects the prepared hydrogels' swelling ability and prolongs their dehydration period. Additionally, the Swelling characteristics of the hydrogels were evaluated at different pHs. Results showed an increase in the swelling ability of all samples by raising the pH value of the medium. Additionally, it was proved that both swelling and dehydration of the hydrogels follow non-Fickian diffusion. In vitro drug delivery experiments demonstrated that the cumulative fractional release of amoxicillin was adversely dependent on the amount of incorporated montmorillonite into the hydrogels and positively dependent on the pH of the release solution. It was also found that, in all examined samples, the mechanism by which the release of clindamycin happens is non-Fickian or anomalous transport. [ABSTRACT FROM AUTHOR]

Rainfall infiltration softens the filling material of deep cracks in expansive soil, significantly reducing its mechanical strength and causing slope instability and failure. Investigating this influence is crucial for preventing slope disasters. This study established a model with a weak interlayer to conduct rainfall infiltration tests on an expansive soil slope. Analyzing the moisture absorption and deformation model test results, the study delved into the temporal and spatial variations of the slope’s seepage field. It also clarified the evolution characteristics and action modes of the strain field under seepage influence. Results indicate that runoff leads to pooling at the slope foot, causing significant softening and swelling. The seepage and deformation fields exhibit a “start-rapid growth-slow growth-tend to stability” pattern on the time curve. Soil affected by rainfall infiltration is concentrated at depths of 10–20 cm. The start-up stage of deep soil displacement change is primarily due to water infiltration delay, intensifying with depth. The weak interlayer weakens and is destroyed after moisture absorption, resulting in the upper slope losing support force, leading to continued collapse and slope failure. The research provides a systematic understanding of the mechanism and failure mode of slope disasters, verifying and analyzing permeability, swelling, shrinking, and seepage characteristics of expansive soil. [ABSTRACT FROM AUTHOR]

The swelling properties of polyacrylonitrile gel prepared by the repeating cycle of freezing and thawing were examined, as its transient response toward the equilibrium swollen states varies with the variation of mixing ratio (r) of the immersion solvent which consisted of N, N–dimethylacetamide and benzene. Two experimental protocols were used; successive solvent exchanges were conducted in Protocol 1, and no solvent exchange but the varying of the volume of immersion solvent was conducted in Protocol 2. Also, the aging time was set between the end of the freezing and thawing cycle and the start of the swelling experiment. As a result, the equilibrium swelling ratio decreased with the increase in the aging time. Significant discrepancies for the transient responses were found for the immersion solvents between r ≤ 0.74 and r ≥ 0.78 both in Protocol 1 and 2, in which the elution of polyacrylonitrile molecules was related to the responses. A characteristic overshoot curve was observed in the swelling with r ≥ 0.78 in Protocol 2, which was also attributed to the polyacrylonitrile elution. The polymer solvent interaction parameter was calculated on the basis of the osmotic pressure equilibrium, which was associated with the interpretation of the transient response data. [ABSTRACT FROM AUTHOR]

We conducted an experimental study on the swelling–shrinking characteristic of expansive soil treated with enzyme-induced carbonate precipitation (EICP) using yellow soybean. A series of tests including the free swell test, swelling rate test, swelling pressure test, and shrinking test were conducted on expansive soil specimens with various water contents and equimolar concentrations. The test results showed that EICP-treated expansive soil samples exhibited an obvious reduction in the magnitude of free swelling rate, swelling rate, swelling pressure, and shirking rate compared with the untreated one. This indicates that EICP using yellow soybean can effectively reduce the swell and shrink potential of expansive soil. The free swelling rate consistently decreases with the increasing equimolar concentration. A more remarkable reduction in swelling rate can be observed at a concentration of 1 mol/L compared with a less significant decrease at a higher concentration. The free swelling rate shows an ascending trend first and then a declining tendency with the increase of water content at higher equimolar concentrations. The influences of equimolar concentration and water content on the change of swelling rate for treated samples with applied loading pressures are insignificant. The swelling pressure reduces remarkably with increasing equimolar concentration and then tends to level off. The swelling pressure exhibits an ascending tendency with the increase of water content. The shrinking rate reduces more remarkably with equimolar concentration at first and then increases less remarkably, with an equimolar concentration of 2 mol/L exhibiting the lowest shrinking rate. The soil specimen with higher water content shows a higher value of shrinking rate than that with a lower one. [ABSTRACT FROM AUTHOR]

The feasibility of introducing optical nonlinearity in poly-dimethyl siloxane (PDMS) using organic solvent swelling was investigated. The third-order nonlinear refraction and absorption properties of the individual materials, as well as the PDMS/solvent compounds after swelling were characterized. The well-established Z-scan technique served as characterization method for the nonlinear properties under picosecond pulsed laser excitation at a 532 nm wavelength. These experiments included investigations on the organic solvents nitrobenzene, 2,6-lutidine, and toluene, which showed inherent optical nonlinearity. We showed that nitrobenzene, one of the most well-known nonlinear optical materials, has proven suboptimal in this context due to its limited swelling effect in PDMS and comparatively high (non)linear absorption, resulting in undesirable thermal effects and potential photo-induced damage in the composite material. Toluene and 2,6-lutidine not only exhibited lower absorption compared to nitrobenzene but also show a more pronounced swelling effect in PDMS. The incorporation of toluene caused a weight change of up to 116% of PDMS, resulting in substantial nonlinear optical effects, reflected in the nonlinear refractive index of the PDMS/toluene composite n2=3.1×10−15 cm2/W.

Abstract Background After total knee arthroplasty (TKA), patients have limited knee range of motion (ROM), trophic changes and pain. Cryotherapy and compression are recommended in the literature, but no study has shown that cryotherapy and compression combined leads to better results than cryotherapy alone. The primary objective was to compare knee ROM after 21 days of rehabilitation post-TKA between patients who underwent rehabilitation with compressive cryotherapy with those who had cryotherapy alone. The secondary objectives were to compare other trophic, pain and functional outcomes. Methods Forty patients were randomized into two groups: Standard Cryotherapy (SC = 20, median age 77 years), which applied cold packs along with their rehabilitation; and Compressive Cryotherapy (CC = 20, median age 76 years), which received cold compression. Knee joint’s passive and active ROM (primary outcome) were measured with a goniometer. Knee’s circumference, fluctuation test, pain at rest and during activity, 6-minute walking test (6MWT) and KOOS questionnaire were secondary outcomes. The groups were compared on D1 (baseline) and D21 of rehabilitation. A survival analysis has compared the groups on D1, D8, D15, D21. Results All subjects had a significant improvement in all the parameters on D21 relative to D1 (p

Abstract Background The various physical and chemical conditions within the oral cavity are hypothesized to have a significant influence on the behavior of denture adhesives and therefore the overall comfort of denture wearers. As such, this study aims to understand the influence of oral cavity physiological parameters such as temperature (17 to 52 °C), pH (2, 7, 10), and denture adhesive swelling due to saliva (20–120%) on the behavior of denture adhesives. This study further aims to emphasize the need for a collective approach to modelling the in-situ behavior of denture adhesives. Methods Rheological measurements were carried out using the Super Polygrip Ultra fresh brand denture adhesive cream to evaluate its storage modulus (G´) and loss modulus (G´´) values at a range of physiologically relevant temperatures, pH values, and degrees of swelling, to represent and characterize the wide variety of conditions that occur within the oral cavity. Results Rheological data was recorded with respect to variation of temperature, pH, and swelling. Overall, it can be seen that the physiological conditions of the oral cavity have an influence on the rheological properties of the denture adhesive cream. Specifically, our data indicates that the adhesive’s mechanical properties are weakly influenced by pH, but do change with respect to the temperature in the oral cavity and the swelling rate of the adhesive. Conclusions Our results suggest that the collective inter-play of the parameters pH, temperature and swelling ratio have an influence on the behavior of the denture adhesive. The results clearly highlight the need for developing a multi-parameter viscoelastic material model to understand the collective influence of physiological parameters on the performance of denture adhesives. Multi-parameter models can also potentially be utilized in numerically simulating denture adhesives using finite element simulations.

Objective To observe the effect of thunder-fire moxibustion on joint function recovery after surgery for fractures around the knee. Methods Totally 50 patients were divided into 2 groups (control group and observation group) by random number method. The control group was treated with routine treatment and nursing interventions after surgery, and the observation group was treated with thunder-fire moxibustion on the basis of routine treatment. The clinical effect of the two groups was compared. Results A total of 48 patients were followed up with complete results, including 24 cases in the control group and 24 cases in the observation group. The upper and lower diameters of the affected limb in the observation group were smaller than those in the control group after 3 and 7 days of treatment, with a significant difference(P＜0. 05). The Visual Analogue Scale (VAS) score of the observation group was significantly lower than that of the control group after 3, 5 and 7 days of treatment, with a significant difference(P＜0. 05). After 1, 3 and 5 weeks of treatment, the Hospital for Special Surgery (HSS) knee scores in two groups were higher than those before treatment (P＜0. 05), and the HSS knee score in the observation group was higher than that in the control group after 3 and 5 weeks of treatment (P＜0. 05). The range motion of the knee in the observation group was better than that of the control group after 7 days of treatment, with a significant difference(P＜0. 05). Conclusion Postoperative nursing combined with thunder-fire moxibustion can effectively reduce the swelling and pain of the affected limb, improve the range of motion and function of the knee joint, and improve the clinical treatment effect. (目的 观察雷火灸联合护理干预促进膝关节周围骨折术后关节功能恢复的效果。方法 采用随机数字表法将50例患者分为对照组和观察组。对照组给予常规治疗和护理, 观察组在对照组基础上增加雷火灸治疗。比较两组干预效果。结果 随访共得到48例患者完整结果, 对照组及观察组各24例。治疗3 d、7 d后, 观察组患者患侧上、下周径均小于对照组, 差异有统计学意义(P＜0. 05)。治疗3 d、7 d后, 观察组患者患侧VAS评分低于对照组, 差异有统计学意义(P＜0. 05)。治疗1周、3周、5周后, 观察组患者患侧膝HSS评分均较治疗前提高(P＜0. 05); 治疗3周、 5周后, 观察组患者患侧膝HSS评分高于对照组(P＜0. 05)。治疗7 d后, 观察组患者患侧膝关节活动度大于对照组, 差异有统计学意义(P＜0. 05)。结论 膝关节周围骨折术后护理配合实施雷火灸治疗, 能有效减轻患肢肿胀、疼痛, 促进康复, 改善膝关节活动度及功能, 有利于提高临床治疗效果。)

The dimensional stability and equilibrium moisture content (EMC) of thermally modified hardwoods were studied. Lumber of yellow-poplar (Liriodendron tulipifera); red oak (Quercus borealis); white ash (Fraxinus americana), red maple (Acer rubrum); hickory (Carya glabra), and black cherry (Prunus serotina) were modified in industrial thermo-vacuum system. The water absorption rate, EMC, swelling, anti-swelling efficiency, shrinkage, anti-shrinkage efficiency, and anisotropy of the specimens were measured and compared to unmodified wood. The results show that thermal modification significantly decreased water absorption of wood which leads to improved dimensional stability. Specifically, thermally modified wood showed reduced EMC (22% in hickory to 59% in red maple), increased water absorption repellent (14.9% in black cherry to 29.6% in yellow-poplar), increased anti-swelling efficiency (14.2% in hickory to 71.4% in ash), increased anti-shrinkage efficiency (23.5% in red maple to 65.6% in ash), and reduced anisotropy coefficient (4.7% in red oak to 31.9% in black cherry).

Abstract Background Minimally invasive approaches to the hip joint for total hip arthroplasty such as the DAA (“Direct Anterior Approach with bikini incision”) are increasingly utilized. According to the literature, this approach is more muscle-sparing, results in less postoperative pain, and achieves higher patient satisfaction. The existence of postoperative lymphedema after hip arthroplasty is hardly considered. The aim of this paper is to contribute to the evaluation of the different access methods related to postoperative lymphedema and their functional outcomes. Methods This is a prospective non-randomized study at an orthopedic specialist clinic in Northern Europe. The surgeons that performed the arthroplasties are high-volume surgeons in private practice affiliated to the clinic. The study included 188 patients with primary hip arthroplasty in a 1:1 ratio (DAA: standard accesses (posterior, transgluteal, and anterolateral access)). Epidemiologic data, Harris Hip Score, Oxford Hip Score, European Quality of Life 5, and Visual Analog Scale were collected preoperatively on admission day, 3rd and 5th postoperative day, and follow-up after 1 year. Furthermore, the range of motion, gait, and ability to climb stairs, as well as the presence of hypesthesia were assessed. To evaluate the edema situation, both legs were measured on the 3rd and 5th postoperative day. The prescription of manual lymphatic drainage and remaining swelling conditions 1 year postoperatively were recorded. Results For each group, 94 patients with a mean age of 61.7 years (DAA 60.7 and standard access 62.6) were included. All but one patient in the DAA group showed postoperative lymphedema (n: 93/94; 98.9%). In the standard surgery group, only n: 37/94 (39.4%) showed swelling symptoms requiring treatment. After 1 year, lymphedema persisted in 20 patients in the DAA group and 0 patients in the standard-OR group. Hypesthesia at the ventral thigh persisted in 16/94 (= 17%) patients of the DAA group versus 0/94 patients of the standard group after 12 months. Of these 16 cases, 10 had concomitant edema (62.5%). The DAA showed better results than the standard accesses in terms of Oxford Hip Score (p 0.05). Conclusion The present study demonstrated the increased incidence of postoperative lymphedema in patients operated on via DAA access using a Bikini-type skin incision. In the follow-up, significantly more hypesthesia of the ventral thigh occurred in the DAA group. Otherwise, the DAA proved to be superior to the standard approaches from a functional point of view at short-term follow-up. Future research is needed to compare the horizontally oblique to the longitudinal oblique skin incision technique in direct anterior hip surgery regarding the above-mentioned adverse effects found in this study.

The purpose of this paper is to investigate some rheological properties (viscosity and swelling) and organoleptic characteristics of the biscuit dough consisting of the natural or alkalized cacao and carob. Natural or alkalized cacao and medium thermally treated carob increase the dough viscosity, and, in the case of both types of cacao, this effect is more significant than in the case of carob, which is caused by weaker extraction of water-soluble components from carob powder. In the case of natural or dark carob, the dough viscosity decreases with an increase in their contents because no additional dough structuring takes place with these additives. Dough swelling and porosity also depend on the additive’s nature. Alkalized and natural cacao increase swelling, porosity, and friability of dough. A similar, but weaker effect was registered for the medium-treated carob, while natural and dark carob decrease these organoleptic characteristics of dough and lower the consumer quality of confectionery. The medium-treated carob powder can be recommended as a cacao substitute for decaffeinated bakery items of other confectionery with special dietary requirements.

ABSTRACTThe most common genetic Creutzfeldt-Jakob disease (gCJD) in Japan is caused by a point mutation in which isoleucine replaces valine at codon 180 of the prion protein (PrP) gene (V180I gCJD). Evidence suggests that cerebral cortex swelling, which appears as abnormal hyperintensities on diffusion-weighted imaging (DWI), is a characteristic magnetic resonance imaging (MRI) finding of V180I gCJD. However, no study has directly compared the MRI findings between V180I gCJD and sporadic CJD (sCJD). The current study, therefore, aims to clarify the imaging features of V180I gCJD, which would lead to prompt genetic counselling and analysis of the PrP gene, particularly focusing on cerebral cortex swelling. We included 35 patients with sCJD (n = 23) or V180I gCJD (n = 12). Cerebral cortex swelling on T2-weighted imaging (T2WI) or fluid-attenuated inversion recovery (FLAIR) wherein abnormal cortical hyperintensities were observed on DWI, and the distribution of grey matter hyperintensities on DWI were visually evaluated. V180I gCJD patients had significantly more cerebral cortex swelling (100% vs. 13.0%, p

The study aims to understand the effect of different admixtures on improving the quality of flexible pavement subgrades. In this paper, recycled concrete aggregates (RCA) and Fly Ash were used as the admixtures in improving the maximum dry density (MDD), swelling potential, and California bearing ratio (CBR) of subgrade soil. The percentages of RCA and fly Ash used were 5%, 10%, and 15%. With the upscaling in fly ash dosage, the optimum moisture content and the California bearing ratio increased. However, the MDD of soil decreased for higher fly ash contents. On the contrary, the optimum moisture content (OMC) of the soil decreased and the MDD and California Bearing Ratio increased with an increase in RCA content. Both RCA and fly ash-treated soil demonstrated lower values of swelling. At 5% dosage, both RCA and fly ash admixtures were found to improve CBR. However, at higher percentages (10% and 15%) of fly ash, the CBR values decreased while in comparison, soil samples performed significantly better in the CBR test with the increasing dosage of RCA. The findings of this research can be used to examine the suitability and effects of recycled aggregate and fly ash on the performance of soil in terms of CBR, particularly when the soil is planned to be used as a subgrade in highways.

Abstract Pressure‐induced swelling has been reported earlier for several hydrophilic layered materials. MXene Ti3C2Tx is also a hydrophilic layered material composed by 2D sheets but so far pressure‐induced swelling is reported for this material only under conditions of shear stress at MPa pressures. Here, high‐pressure experiments are performed with MXenes prepared by two methods known to provide “clay‐like” materials. MXene synthesized by etching MAX phase with HCl+LiF demonstrates the effect of pressure‐induced swelling at 0.2 GPa with the insertion of additional water layer. The transition is incomplete with two swollen phases (ambient with d(001) = 16.7Å and pressure‐induced with d(001) = 19.2Å at 0.2 GPa) co‐existing up to the pressure point of water solidification. Therefore, the swelling transition corresponds to change from two‐layer water intercalation (2L‐phase) to a never previously observed three‐layer water intercalation (3L‐phase) of MXene. Experiments with MXene prepared by LiCl+HF etching have not revealed pressure‐induced swelling in liquid water. Both MXenes also show no anomalous compressibility in liquid methanol. The presence of pressure‐induced swelling only in one of the MXenes indicates that the HCl+LiF synthesis method is likely to result in higher abundance of hydrophilic functional groups terminating 2D titanium carbide.

A superabsorbent polymer, Sodium Alginate-g-Poly (Itaconic acid-co-Sodium 4-vinyl benzenesulfonate)/ Ricinus communis (SA-g-P(ITA-co-VBS)/ RC) hydrogel, was prepared by free-radical graft co-polymerization for sequestration of toxic malachite green (MG) dye as a cationic dye model. The surface morphological of shape and composition of the prepared hydrogel used have been characterized by FESEM, EDX, TEM, FTIR, X-ray diffraction XRD, and TGA. Optimizing the synthesis conditions for prepared a hydrogel with the highest swelling ratio have been studied, the results show that employing 0.08 g KPS and 0.09 g MBA, 1.0 g ITA, 2.0 g VBS, 1.0 g SA, and 1.0 g RC, the composites greatest swelling capacity in distilled water was 3400 %. It was discovered that the dye adsorption capacity of the polymer was greatly impacted by the monomer VBS level in the hydrogel, which gives it a better ability to swell. The porosity of the hydrogel spheres, thus significantly enhancing the MG adsorption capacity with the rate-limiting controlled by chemical adsorption, intraparticle diffusion, and film diffusion. Study the influence of different reaction conditions on the removal of MG dye from aqueous solution are adsorbent dose, pH, zero-point charge, temperature, thermodynamic adsorption, adsorption isotherm, and kinetic models have been done. Additionally, (SA-g-P(ITA-co-VBS)/RC) demonstrated strong MG dye adsorption capabilities and reusability in at least four adsorption-desorption cycles this process indicating its considerable potential for use as the adsorbent for dye removals from aqueous solution.

Background: After total knee arthroplasty (TKA), patients have limited knee range of motion (ROM), trophic changes and pain. Cryotherapy and compression are recommended in the literature, but no study has shown that cryotherapy and compression combined leads to better results than cryotherapy alone. The primary objective was to compare knee ROM after 21 days of rehabilitation post-TKA between patients who underwent rehabilitation with compressive cryotherapy with those who had cryotherapy alone. The secondary objectives were to compare other trophic, pain and functional outcomes. Methods: Forty patients were randomized into two groups: Standard Cryotherapy (SC = 20, median age 77 years), which applied cold packs along with their rehabilitation; and Compressive Cryotherapy (CC = 20, median age 76 years), which received cold compression. Knee joint's passive and active ROM (primary outcome) were measured with a goniometer. Knee's circumference, fluctuation test, pain at rest and during activity, 6-minute walking test (6MWT) and KOOS questionnaire were secondary outcomes. The groups were compared on D1 (baseline) and D21 of rehabilitation. A survival analysis has compared the groups on D1, D8, D15, D21. Results: All subjects had a significant improvement in all the parameters on D21 relative to D1 (p <.05), except for pain at rest (p =.065 for CC and p =.052 for SC). On D21, the CC group had a significantly larger improvement in the joint effusion (p =.002), pain during activity (p =.005), 6MWT (p =.018) and KOOS (p =.004) than the SC group. Based on the survival analysis, the CC group had significantly faster improvement in the joint ROM (p =.011 for flexion and p =.038 for extension) and knee circumference (p =.013) than the SC group. Conclusions: Both cryotherapy methods improved joint ROM, trophic changes, pain and function. Adding dynamic compression to a cryotherapy protocol provided further benefits: a significantly faster improvement in passive knee flexion ROM, a greater reduction of swelling, and pain during activity. Similarly, walking distance and KOOS questionnaire were significantly better for CC. Trials registration: The study was registered in the ClinicalTrials.gov database on 14/09/2023 (identifier: NCT06037824). [ABSTRACT FROM AUTHOR]

Superabsorbent composites (SC) can be defined as filler-enriched absorbent polymer chemistry. The superabsorbent polymers are made up of hydrophilic polymers with added cross-linking systems and tend to absorb, swell and retain a substantial volume of water. The conventional chemistries are based on synthetic polymers mainly acrylics. Concerning the fossil fuel crisis, their price depletion and to make the superabsorbent compounds more eco-friendly various biobased materials are incorporated into the structure to make the systems eco-friendlier and more sustainable. The biobased compounds widely explored in such areas are starch, cellulose, guar gum, xanthan gum, alginate, etc. The filler namely various clays such as montmorillonite (MMT), Attapulgite (APT), Kaolin, and bentonite in carbon-based fillers carbon nanotubes (CNT), graphite oxide, and various biobased compounds such as proteins, and biobased waste such as wheat straw, rice husk ash, and miscellaneous fillers as semi-coke, layered double hydroxides are well studied in the SC area. The performance of SC depends upon various reaction parameters such as monomers, initiator, modifier, filler, temperature, and time as well on other factors such as pH of the medium and particle size. The SC is found in a variety of application areas such as drug delivery, agriculture, wastewater treatment, the construction industry, sanitary napkins and diapers, food preservation, and artificial snow. [ABSTRACT FROM AUTHOR]

Large scale computer simulations are employed to analyze the conformations of network strands in polymer networks at preparation conditions (characterized by a polymer volume fraction of ϕ0) and when swollen to equilibrium (characterized by a polymer volume fraction ϕ < ϕ0). Network strands in end‐linked model networks are weakly stretched and partially swollen at preparation conditions as compared to linear polymers in the same solvent at ϕ0. Equilibrium swelling causes non‐ideal chain conformations characterized by an effective scaling exponent approaching 7/10 on intermediate length scales for increasing overlap of the chains. The chain size in a network consists of a fluctuating and a time average “elastic” contribution. The elastic contribution swells essentially affinely ∝(ϕ0/ϕ)2/3, whereas the swelling of the fluctuating part lies between the expected swelling of the entanglement constraints and the swelling of non‐cross‐linked chains in a comparable semi‐dilute solution. The total swelling of chain size results from the changes of both fluctuating and non‐fluctuating contributions. [ABSTRACT FROM AUTHOR]